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x r y R bjbj { { !9 s j j " " " ~" *& <" W fH LK bK bK ,L M : $ P Ԧ = " N Ԧ j j bK ,L S o o o j bK j < bK o o o R | z bK poH k j ' 0 W r ٮ / @ ٮ z ٮ " z o Ԧ Ԧ o W ٮ , 0 : DN1
SYTvsQhel6ROiQh
^S el
Ty {|W R:N
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4 2PBRhel
4 . 1 2uW_{VUIUnI{2 3 *N~R
4 . 2 !Tkx I{1 9 *N~R
4 . 3 ][NYNWxx vI{7 y~R
4 . 4 Z(lNWS̀
4 . 5 wmKQfvU
4 . 6 |xx^l
4 . 7 2uxI{9 y~R
4 . 8 2u
4 . 9 8ny2u ,{Vz tShel
4 2PBRhel
4 . 1 2u
4 . 2 2uxSvQv
4 . 3 'l_N
4 . 4 Nb/l
4 . 5 Rb/l0Ă"}/lTN/l
4 . 7 2uW/l_{VUIUnI{1 2 y~R
4 . 8 /lu
4 . 9 N/laSs
4 . 1 0 q\hxT1"lYNx
4 . 1 1 4lhgxI{5 y~R !Tkx I{1 9 *N~Rhel ][NYNWxx vI{7 y~Rhel Z(lNWS̀hel wmKQfvUhel |xx^lhel 2uxI{9 y~Rhel ,{Vz tShel 4 2PBRhel
4 . 6 2u ^Ste ,{Vz tShel 4 2PBRhel 4 . 1 2 8ny2uV[oTvcw{t@\2 0 1 9 t^,{1 2 SJT ^Ste 2 SYT-N|xxT|xxvhel O ,{Vz tShel 3 P(u~Rhel 3 . 7 |xxT|xxv ,{Vz tShel 3 P(u~Rhel 3 . 7 |xxT|xxv 3 SYT-N[NI{3 2 y~Rhel O ,{Vz tShel 7 gSBRhel
7 . 2 [NI{3 2 y~R ,{Vz tShel 7 gSBRhel 7 . 2 [NI{3 2 y~R 4 SYT-N~2uxI{8 y~Rhel O ,{Vz tShel 2 y(u~Rhel 2 . 2 8 ~2uxI{8 y~R ,{Vz tShel 2 y(u~Rhel 2 . 2 8 ~2uxT_~2ux 5 SOYTsNRir~ހ_8hՋ eX ,{mQz ktf[Ջel 2 5 SOYTsNRir~ހ_8hՋ 6 SYT[ye}vRHeKmՋel eX ,{kQz NSORHeċNhel 5 SYT[ye}vRHeKmՋel 7 SYT21SRHeKmՋel eX ,{kQz NSORHeċNhel 6 SYT21SRHeKmՋel
DN2
4 2PBRhel
D e t e r m i n a t i o n o f p r e s e r v a t i v e s i n c o s m e t i c s
,gRĉ[NSYT-N2PBRvhel T_Km~RN
0SYT[hQb/gĉ2 0 1 5 t^Hr 0Q(u2PBR,{ Nz h4 v[^sQ|SǑ(uvhelh1 Thelmvv_Km~Rh2 0
h1
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0SYT[hQb/gĉ2 0 1 5 t^Hr 0
Q(u2PBR,{ Nz h4
^ST
Ty _Km~R hel 1 2 - n- 2 - ]xWNp- 1 , 3 - N 2 - n- 2 - ]xWNp- 1 , 3 - N 4 . 1 2 5 - n- 5 - ]xW- 1 , 3 - NAVp 5 - n- 5 - ]xW- 1 , 3 - NAVp 4 . 1 3 7 - YNWSsAVUIU 7 - YNWSsAVUIU 4 . 7 4 pW( C 1 2 - C 2 2 ) N2uWnSirb/lSir ASNpW N2uWnS 4 . 3 5 Nb/l, Nbn, Nb|| ASNpWN2uWĂW/lS 4 . 3 ASVpWN2uWĂW/lS ASmQpWN2uWĂW/lS 6 Ă"}/l Ă"}/l 4 . 3 7 2uxSvQv{|To{| 2ux 4 . 1 2ux2uo 4 . 2 2uxYNo 4 . 1 2uxNo 4 . 1 2ux_No 4 . 1 2uxWo 4 . 1 2uxNo 4 . 7 2ux_No 4 . 7 8 2u 2u 4 . 1 1 0 n/l n/l 4 . 2 1 1 /l][SvQNa|xv, Nxv /l][ 4 . 3 1 2 N/lSN N/lSN 4 . 7 1 3 Ă/lZ Ă/lZ 4 . 2 1 4 /lN2uZ /lN2uZ 4 . 2 1 5 /lu /lu 4 . 1 1 6 /lT]U /lT]U 4 . 2 1 7 1"lYNxSvQv{| 1"lYNx 4 . 1 2 0 N/l2u 2 , 6 - N/l2u 4 . 2 2 , 4 - N/l2u 2 1 N2uWAVUp N2uWAVUp 4 . 7 2 4 2uxSvQv 2ux 4 . 7 2 5
bN
bN 4 . 7 2 6 ][SvQv, Sb][N*NYNWxxvT][[W2uxv ][NYNWxx v 4 . 3 2 7 wmKQfvU wmKQfvU 4 . 5 3 0 xNpNW(l2uxo xNpNW(l2uxo 4 . 2 3 1 2uW_{VUIUn 2uW_{VUIUn 4 . 1 3 2 2uW/l_{VUIUnT2uW_{VUIUnN/lSAS]xxAvmTir 2uW/l_{VUIUn 4 . 1 3 3 Op- 5 - Op- 5 - 4 . 2 3 4 WZSvQv{| WZ 4 . 2 3 5 4 - W2uxSvQv{|To{| 4 - W2ux 4 . 1 4 - W2ux_No 4 - W2ux_No 4 - W2uxNo 4 - W2ux2uo 4 - W2uxYNo 4 - W2uxNo 4 - W2uxo 4 - W2uxĂo 4 - W2ux
bo 3 6 [/l2uZ [/l2uZ 4 . 2 3 7 'lYN 'lYN 4 . 1 3 8 'l_N 'l_N 4 . 2 3 9 !TWKQnT!TWKQnYNv !TWKQnYNv 4 . 2 4 0 Z(lNWS̀ Z(lNWS̀ 4 . 4 4 1 NxSvQv{| Nx 4 . 7 4 2 4lhgxSvQv{| 4lhgx 4 . 2 4 3 ^lvv{|, Sb|xx^l |xx^l 4 . 6 4 6 q\hxSvQv{| q\hx 4 . 2 4 7 kxg^l kxg^l 4 . 2 4 8 N/laSs N/laSs 4 . 2 4 9 N/l u N/l u 4 . 2 5 0 AS NpxSvQv{| AS Npx 4 . 7 5 1 !Tkx !Tkx 4 . 2 h2 helmvv_Km~ROo`h
^S hel
Ty _Km~R 4 . 1 2uW_{VUIUnI{2 3 *N~R 2uW_{VUIUn 2 - n- 2 - ]xWNp- 1 , 3 - N 4 - W2ux 2uW/l_{VUIUn 2u 'lYN 2ux 4 - W2ux2uo /lu 1"lYNx 5 - n- 5 - ]xW- 1 , 3 - NAVp 4 - W2uxYNo 4 - W2ux_No 4 - W2uxNo 4 - W2uxo 4 - W2ux_No 4 - W2uxNo 4 - W2uxĂo 2uxYNo 4 - W2ux
bo 2ux_No 2uxNo 2uxWo 4 . 2 !Tkx I{1 9 *N~R !Tkx 4lhgx q\hx 'l_N 2 , 6 - N/l2u 2ux2uo xNpNW(l2uxo [/l2uZ 2 , 4 - N/l2u WZ Op- 5 - /lN2uZ /lT]U Ă/lZ !TWKQnYNv N/laSs N/l u n/l kxg^l 4 . 3 ][NYNWxx vI{7 y~R ][NYNWxx v /l][ ASNpW N2uWnS ASNpWN2uWĂW/lS Ă"}/l ASVpWN2uWĂW/lS ASmQpWN2uWĂW/lS 4 . 4 Z(lNWS̀ Z(lNWS̀ 4 . 5 wmKQfvU wmKQfvU 4 . 6 |xx^l |xx^l 4 . 7 2uxI{9 y~R 2ux Nx N/lSN 2ux_No 2uxNo AS Npx 7 - YNWSsAVUIU N2uWAVUp
bN
4 . 1 2uW_{VUIUnI{2 3 y~R
M e t h y l i s o t h i a z o l i n o n e a n d o t h e r 2 2 k i n d s o f c o m p o n e n t s
1 V
,gelĉ[NؚHemvr1lKm[SYT-N2uW_{VUIUnI{2 3 y~Rv+Tϑ0
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,gel@bcv2 3 y~RSb2uW_{VUIUn02 - n- 2 - ]xWNp- 1 , 3 N04 - W2ux02uW/l_{VUIUn02u0'lYN02ux04 - W2ux2uo0/lu01"lYNx05 - n- 5 - ]xW- 1 , 3 - NAVp04 - W2uxYNo04 - W2ux_No* 04 - W2uxNo04 - W2uxo* 04 - W2ux_No* 04 - W2uxNo04 - W2uxĂo* 02uxYNo04 - W2ux
bo* 02ux_No02uxNoT2uxWo0
l* bR
N^\N
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,gel-NT~RvhQP0[ϑ NPTS7hϑ:N1 g evhQSm^0 gNO[ϑSm^h1 0
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Ty hQP
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g / g gNO[ϑSm^g / g 1 2uW_{VUIUn 0 . 2 0 0 . 6 0 0 . 2 0 0 . 6 0 2 2 - n- 2 - ]xWNp- 1 , 3 - N 5 . 0 1 5 5 . 0 1 5
3 4 - W2ux 0 . 7 0 2 . 0 0 . 7 0 2 . 0
4 2uW/l_{VUIUn 0 . 2 0 0 . 6 0 0 . 2 0 0 . 6 0 5 2u 1 0 3 0 1 0 3 0 6 'lYN 7 . 0 2 0 7 . 0 2 0 7 2ux 1 . 7 5 . 0 1 . 7 5 . 0 8 4 - W2ux2uo 0 . 4 0 1 . 0 0 . 4 0 1 . 0 9 /lu 1 . 0 3 . 0 1 . 0 3 . 0 1 0 1"lYNx 1 . 0 3 . 0 1 . 0 3 . 0 1 1 5 - n- 5 - ]xW- 1 , 3 - NAVp 8 . 0 2 5 8 . 0 2 5 1 2 4 - W2uxYNo 0 . 8 0 2 . 5 0 . 8 0 2 . 5 1 3 4 - W2ux_No 0 . 8 0 2 . 5 0 . 8 0 2 . 5 1 4 4 - W2uxNo 0 . 8 0 2 . 5 0 . 8 0 2 . 5 1 5 4 - W2uxo 1 . 0 3 . 0 1 . 0 3 . 0 1 6 4 - W2ux_No 1 . 0 3 . 0 1 . 0 3 . 0 1 7 4 - W2uxNo 1 . 0 3 . 0 1 . 0 3 . 0 1 8 4 - W2uxĂo 1 . 0 3 . 0 1 . 0 3 . 0 1 9 2uxYNo 2 . 0 6 . 0 2 . 0 6 . 0 2 0 4 - W2ux
bo 2 . 0 6 . 0 2 . 0 6 . 0 2 1 2ux_No 2 . 0 7 . 0 2 . 0 7 . 0 2 2 2uxNo 2 . 0 7 . 0 2 . 0 7 . 0 2 3 2uxWo 2 . 7 8 . 0 2 . 7 8 . 0 3 ՋBRTPge
dS gĉ[Y ,gel@b(uՋBRGW:NRg~ 4l:NG B / T 6 6 8 2 ĉ[v N~4l0
3 . 1 2u r1~0
3 . 2 YNH r1~0
3 . 3 N2uN x r1~0
3 . 4 xx8 5 % V / V Rg~0
3 . 5 xx4lnmϑSxx3 . 4 1 . 2 m L R4l1 0 0 0 m L m S0
3 . 6 mThQPYnmQnxyS2uW_{VUIUnI{2 3 y~RvhQTϑ |nx0 . 0 0 0 1 g nN T N[ϑt-N HQ(u2 m L N2uN xn Q(uYNH[[;R^ Gd S nN4 !Q{-NQυOX[0T~RSm^h2 0
h2 2uW_{VUIUnI{2 3 y~RmThQPYnmSm^
^S ~R
Ty mThQPYnmSm^g / L 1 2uW_{VUIUn 0 . 6 0 2 2 - n- 2 - ]xWNp- 1 , 3 - N 1 5 3 4 - W2ux 2 . 0 4 2uW/l_{VUIUn 0 . 6 0 5 2u 3 0 6 'lYN 2 0 7 2ux 5 . 0 8 4 - W2ux2uo 1 . 0 9 /lu 3 . 0 1 0 1"lYNx 3 . 0 1 1 5 - n- 5 - ]xW- 1 , 3 - NAVp 2 5 1 2 4 - W2uxYNo 2 . 5 1 3 4 - W2ux_No 2 . 5 1 4 4 - W2uxNo 2 . 5 1 5 4 - W2uxo 3 . 0 1 6 4 - W2ux_No 3 . 0 1 7 4 - W2uxNo 3 . 0 1 8 4 - W2uxĂo 3 . 0 1 9 2uxYNo 6 . 0 2 0 4 - W2ux
bo 6 . 0 2 1 2ux_No 7 . 0 2 2 2uxNo 7 . 0 2 3 2uxWo 8 . 0
4 NhVTY
4 . 1 ؚHemvr1N Ng{5RhKmhV0
4 . 2 XlnmhV0
4 . 3 0 . 2 2 m n0
4 . 4 y_:g0
4 . 5 me/cahV0
4 . 6 )Ys^0
5 Rgek
5 . 1 mThQ|Rnm6RY
SmThQPYnm3 . 6 ϑ (u2u zʑ_mThQ|Rnm T~RhQ|RnmSm^h3 0mThQ|Rnm^s(usM0
h3 2uW_{VUIUnI{2 3 y~RhQ|RnmSm^
~R
Ty mThQ|RnmSm^g / m L 2uW_{VUIUn 0 . 0 6 0 0 . 3 1 . 5 7 . 5 1 5 3 0 2 - n- 2 - ]xWNp- 1 , 3 - N 1 . 5 7 . 5 3 7 . 5 1 8 7 . 5 3 7 5 7 5 0 4 - W2ux 0 . 2 0 1 . 0 5 . 0 2 5 5 0 1 0 0 2uW/l_{VUIUn 0 . 0 6 0 0 . 3 0 1 . 5 7 . 5 1 5 3 0 2u 3 . 0 1 5 7 5 3 7 5 7 5 0 1 5 0 0 'lYN 2 . 0 1 0 5 0 2 5 0 5 0 0 1 0 0 0 2ux 0 . 5 0 2 . 5 1 2 . 5 6 2 . 5 1 2 5 2 5 0 4 - W2ux2uo 0 . 1 0 0 . 5 0 2 . 5 1 2 . 5 2 5 5 0 /lu 0 . 3 0 1 . 5 7 . 5 3 7 . 5 7 5 1 5 0 1"lYNx 0 . 3 0 1 . 5 7 . 5 3 7 . 5 7 5 1 5 0 5 - n- 5 - ]xW- 1 , 3 - NAVp 2 . 5 1 2 . 5 6 2 . 5 3 1 2 . 5 6 2 5 1 2 5 0 4 - W2uxYNo 0 . 2 5 1 . 2 5 6 . 2 5 3 1 . 2 5 6 2 . 5 1 2 5 4 - W2ux_No 0 . 2 5 1 . 2 5 6 . 2 5 3 1 . 2 5 6 2 . 5 1 2 5 4 - W2uxNo 0 . 2 5 1 . 2 5 6 . 2 5 3 1 . 2 5 6 2 . 5 1 2 5 4 - W2uxo 0 . 3 0 1 . 5 7 . 5 3 7 . 5 7 5 1 5 0 4 - W2ux_No 0 . 3 0 1 . 5 7 . 5 3 7 . 5 7 5 1 5 0 4 - W2uxNo 0 . 3 0 1 . 5 7 . 5 3 7 . 5 7 5 1 5 0 4 - W2uxĂo 0 . 3 0 1 . 5 7 . 5 3 7 . 5 7 5 1 5 0 2uxYNo 0 . 6 0 3 . 0 1 5 7 5 1 5 0 3 0 0 4 - W2ux
bo 0 . 6 0 3 . 0 1 5 7 5 1 5 0 3 0 0 2ux_No 0 . 7 0 3 . 5 1 7 . 5 8 7 . 5 1 7 5 3 5 0 2uxNo 0 . 7 0 3 . 5 1 7 . 5 8 7 . 5 1 7 5 3 5 0 2uxWo 0 . 8 0 4 . 0 2 0 1 0 0 2 0 0 4 0 0 l[[S9hnc[E`QteTvhQ|RnmSm^V0
5 . 2 7hTYt
QnxyS7hT1 . 0 g |nx0 . 0 0 1 g nNwQ^Xkr{-N ReQ2u3 . 1 8 m L me/ca3 0 s OՋ7hNcSnBREQRm S XcS2 0 m i n ]\Os2 0 ^4 3 K H z 2 0 0 W (u2u3 . 1 [[1 0 m L Gd S N1 0 0 0 0 r / m i n y_5 m i n 0
Nnm~0 . 2 2 m nǏn Snm\O:N_Kmnm0|{|W(7hTHQReQ1 m L 4l !W7hTHQR1 ^2 m L V"lKTU O7hTGW SRce QReQ2u3 . 1 ۏLcS0
5 . 3 Sr1agN
r1g C 1 8 g5 m 4 . 6 2 5 0 m m bI{Her1g0
AmRvnmA xx4lnm3 . 5 nmB YNH3 . 2 h^m1 z^h4
h4 AmRvh^m1 z^
em i n A ( % ) B ( % ) 0 . 0 0 9 0 1 0 5 . 0 0 9 0 1 0 2 9 . 0 5 0 5 0 4 1 . 0 6 5 3 5 5 2 . 0 3 5 6 5 5 7 . 0 5 9 5 6 2 . 0 9 0 1 0 6 7 . 0 9 0 1 0 Am 1 . 0 m L / m i n
g)n3 0 !
ۏ7hϑ1 0 L
hKml2uW_{VUIUn02uW/l_{VUIUn0'lYN01"lYNxvKm[Ǒ(u2 8 0 n m 4 - W2ux02u04 - W2ux2uo04 - W2uxYNo04 - W2ux_No04 - W2uxNo04 - W2uxo04 - W2ux_No04 - W2uxNo04 - W2uxĂo04 - W2ux
bovKm[Ǒ(u2 5 4 n m 2 - n- 2 - ]xWNp- 1 , 3 - N02ux0/lu05 - n- 5 - ]xW- 1 , 3 - NAVp02uxYNo02ux_No02uxNo02uxWovKm[Ǒ(u2 3 0 n m 01"lYNxvKm[_NS bǑ(u3 1 0 n m 0
5 . 4 Km[
(W 5 . 3 Sr1agN N SmThQ|Rnm5 . 1 R+Rۏ7h ۏLr1Rg NhQ|RnmSm^:N*jPWh \by:N~PWh ~6RhQf~0
S 5 . 2 y Nv_Kmnmۏ7h ۏLr1Rg 9hncOYueT+}YIQV1['` Km_\by 9hnchQf~_0R_Kmnm-NTKm[~RvSm^ c 6 {7hT-NT_Km~Rv+Tϑ0
l1 4 - W2uxN4 - W2uxvOYue N 2uxN2uxvOYue N 1"lYNxN1"lYNxvOYue N Km[~gGWNx02 4 - W2uxNoT4 - W2ux_No:N TR_gSO 4 - W2ux_NoT4 - W2uxĂo
N^\N
0SYT[hQb/gĉ2 0 1 5 t^Hr 0Q(u2PBR~R07hT-NhQ4 - W2ux_Nob4 - W2uxĂoe ^laN4 - W2uxNovRy^ *g0RW~Ry ^ǑS\7RrRvyRe_0
6 Rg~gvh
6 . 1 {
E M B E D E q u a t i o n . 3
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V 7hT[[SOy m L
m 7hTS7hϑ g 0
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l2uxN2ux NxNNxv0AS NpxNAS NpxvOYue N Km[~gGWNx0
6 Rg~gvh
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l a p2 ytd T B D F H $ $If a$ gdd l $$If a$gdd l H J L b 2 $ $If a$ gdd l kd $$If T 4 r =2>'4 7
0 4 4
l a p2 ytd T b d f h $ $If a$ gdd l $$If a$gdd l h j l ~ 2 $ $If a$ gdd l kd $$If T 4 r =2>'4 7
0 4 4
l a p2 ytd T ~ $ $If a$ gdd l $$If a$gdd l 2 $ $If a$ gdd l kd $$If T 4 r =2>'4 7
0 4 4
l a p2 ytd T $ $If a$ gdd l $$If a$gdd l 2 $ $If a$ gdd l kd $$If T 4 r =2>'4 7
0 4 4
l a p2 ytd T $ $If a$ gdd l $$If a$gdd l 2 $ $If a$ gdd l kd $$If T 4 r =2>'4 7
0 4 4
l a p2 ytd T
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l / a p2 ytd T t ~ $$If a$gdd l $ $If a$ gdd l 2 $$If a$gdd l kd $$If T 4 r =2>'4 7
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l a p2 ytd T $$If a$gdd l $ $If a$ gdd l & kd $$If T 4 r =2>'4 7
0 4 4
l / a p2 ytd T " ^ ` $ $If a$ gdd l $$If a$gdd l ` b f 2 $$If a$gdd l kd
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0 4 4
l a p2 ytd T f $$If a$gdd l $ $If a$ gdd l > @ D J z " ̻yk_k_kWkWkWkGkGkW hd B*H*KH OJ QJ ph hd OJ QJ hd B*OJ QJ ph hd B*KH OJ QJ ph hd B*KH OJ PJ QJ ph hd @CJ OJ PJ QJ aJ 'hd B*CJ KH OJ PJ QJ aJ ph hd CJ, OJ PJ QJ aJ, !hd CJ, OJ PJ QJ ^J aJ, o(hd QJ ^J aJ o(hd OJ QJ aJ hd hd hd OJ QJ aJ o(hd hd OJ QJ aJ 2 0 0 ' . $x x a$ kd $$If T 4 r =2>'4 7
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l a T
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l a T w $$If a$
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l a T " $ & @ B ~ ~ ~ ~
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l a T " 0 6 J P f l ( . L R p v 8 > \ b | H N x ~ 8 > v | ( . T Z x ~ & D J d j hd OJ QJ hd B*KH OJ QJ ph U
$$1$If a$t kd $$If T \ ] 4 4
l a T ~ ~ ~ ~
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l a T ~ ~ ~ ~
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l a T ~ ~ ~ ~
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l a T ~ ~ ~ ~
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l a T
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